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Synthesis and structural characterization of five copper(I) complexes of [2,3-f]-pyrazino-[1,10]phenanthroline-2,3-dicarbonitrile and triphenylphosphine

✍ Scribed by Ye-Lan Xiao; Qiong-Hua Jin; Yu-Heng Deng; Zhong-Feng Li; Wei Yang; Man-Hua Wu; Cun-Lin Zhang


Book ID
113661925
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
570 KB
Volume
15
Category
Article
ISSN
1387-7003

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## Abstract A series of tricarbonyl rhenium(I) complexes of the type __fac__‐[Re^I^(CO)~3~(ppl)(L)]^0/+^, where ppl is pyrazino[2,3‐__f__][1,10]phenanthroline, and where L is Cl^−^, TfO^−^, 4‐(__tert__‐butyl)pyridine (^__t__^Bu‐py), 4‐methoxypyridine (MeO‐py), 4,4′‐bipyridyl (bpy), or 10‐(picolin‐4

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A series of substituted pyrazino[2,3-f][1,10]-phenanthroline (Rppl) ligands (with R Me, COOH, COOMe) were synthetized (see 1 ± 4 in Scheme 1). The ligands can be visualized as formed by a bipyridine and a quinoxaline fragment (see A and B). Homoleptic [Ru(R 1 ppl) 3 ](PF 6 ) 2 and heteropleptic [Ru(