Synthesis and structural characterization of a novel dimolybdenum(I) compound with mixed-tribridging ligands: [Bu4N][Mo2(μ-SPh)2(μ-Cl(CO6]

✍ Scribed by Guo-Hua Pan; Bo-Tao Zhuag; Ling-Jie He; Jiu-Tong Chen; Jia-Xi Lu

• Publisher: John Wiley and Sons
• Year: 2010
• Tongue: English
• Weight: 413 KB
• Volume: 18
• Category: Article
• ISSN: 0256-7660
• DOI: 10.1002/cjoc.20000180516

✦ Synopsis

CHINESE JOURNAL OF CHEMElXY u)oo Synthesis and structural characterization of a novel dimolybdenum ( I) compound with mixed-tribridging ligands : [ Bu4N I C M02 ( p-sph) 2( P C ~ ( CO 6 I Molybdam( I) compound, crystal S ~Cture, Mq& unit, &ial bioctahedral s b c t m , IR, NMR, cv ?he study of bimetallic complexes has been .an active research a m as metal-metal interaction generally results in unique physical and chemical p&a. ' In this respect , dinuclear mlybdenum conq>lexes have been extensively in~e&gated.~ To OUT knowledge, however, 90 far a few Mo( I) mmplexea have been s y s d c d y investigated in the literature m p t [CPMO(CO)~]~,'[CP-Mo( C0)2 If and [ Mqcp~ ( COh (p--ph2pcH2P& ) I -'

Recently, an attempt to develop novel Mo(1) ccenplhas been canied out by introducing a variety of function-a l ligand.9 into the parent cumpound Mq(p-SPh),-(CO),6 (2). We describe here synthesis and charact e*m