Synthesis and Structural Characterization of a New Rare-Earth Selenodiphosphate: KLaP2Se6
โ Scribed by Chen, John H.; Dorhout, Peter K.
- Book ID
- 125967495
- Publisher
- American Chemical Society
- Year
- 1995
- Tongue
- English
- Weight
- 269 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0020-1669
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๐ SIMILAR VOLUMES
## Crystals of Ce ุ4 Mn ุ2 2 Ge 4 O 12 and Gd ุ3 Mn ุ3 Ge 2 O 7 were obtained during the exploration of the quaternary Ln-Mn-Ge-O system. Their structures have been determined by single-crystal X-ray diffraction: CeMn 2 Ge 4 O 12 crystallizes in the tetragonal space group P4/nbm with a โซุโฌ 9.816(1
The reaction of rare earth silylamides Ln[N(SiHMe 2 ) 2 ] 3 (thf) n performed on the solvent-free, dinuclear yttrium derivative 5 revealed an unusual ยต 2 ,ฮท 4 :ฮท 1 -coordination of the [n = 1 for Sc (1a); n = 2 for Y (1b), La (1c), Nd (1d)] with trans-1,2-bis(2,4,6-triisopropylbenzenesulfonamido)cyc