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Synthesis and Structural Characterization of a New Family of Layered Intergrowth Phases Based on Antimony(III) Oxide

✍ Scribed by Christopher D. Ling; John G. Thompson; Ray L. Withers; Siegbert Schmid


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
801 KB
Volume
125
Category
Article
ISSN
0022-4596

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Ba3Te2O6X2 is obtained by reacting TeO2 in a BaX2 flux at 1000 °C under atmospheric conditions. The samples are characterized by powder and single crystal XRD. All four compounds crystallize in the cubic space group Fd3m with Z = 16. The structures consist of a rigid ∞ 3 [M3Te2O6] 2+ framework (M: S