Synthesis and structural characterization of 3d-metal complexes of pyridine-4-carboxaldehyde thionicotinoyl hydrazone
โ Scribed by Nand K. Singh; Rajesh Tripathi
- Publisher
- Springer
- Year
- 1988
- Tongue
- English
- Weight
- 338 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0340-4285
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract The synthesis of a novel pyridine diphosphite ligand 1 has been described. From this ligand, rhodiumโ and iridiumโchlorido complexes of formula [MCl(1)] (M = Rh, Ir) have been prepared. Chloride abstraction by treatment with NaBPh~4~ and a phosphane produced the corresponding cationic p
The reaction of rare earth silylamides Ln[N(SiHMe 2 ) 2 ] 3 (thf) n performed on the solvent-free, dinuclear yttrium derivative 5 revealed an unusual ยต 2 ,ฮท 4 :ฮท 1 -coordination of the [n = 1 for Sc (1a); n = 2 for Y (1b), La (1c), Nd (1d)] with trans-1,2-bis(2,4,6-triisopropylbenzenesulfonamido)cyc