The ligands [Ph 2 (S)PNHP(X)Ph 2 ] -(X = O, Se) react with InCl 3 coordination geometry in 2 resembles that observed in the three analogous tris-chelates incorporating the corres-in a 3:1 ratio to give a tris-chelate [In{Ph 2 P(O)NP(S)Ph 2 -O,S} 3 ]•0.75 C 6 H 6 (2) and the unexpected pentacoordinat
✦ LIBER ✦
Synthesis and structural characterisation of tris(diphenylthiophosphinoyl)methane and tris(diphenylthiophosphinoyl)methanide complexes of rhodium and iridium; X-ray structures of [Rh(C8H12){η2-C(P(S)Ph2)3-S,S}] and [Ir(CO)2{gh2-C(P(S)Ph2)3-S,S}]
✍ Scribed by Jane Browning; Keith R. Dixon; Robert W. Hilts; Neil J. Meanwell; Fang Wang
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 819 KB
- Volume
- 410
- Category
- Article
- ISSN
- 0022-328X
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