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Synthesis and structural characterisation of some novel lithium and sodium N,N???-di(para-tolyl)formamidinate complexes

✍ Scribed by Cole, Marcus L.; Junk, Peter C.; Louis, Lance M.

Book ID
120458753
Publisher
The Royal Society of Chemistry
Year
2002
Tongue
English
Weight
353 KB
Volume
20
Category
Article
ISSN
1472-7773

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## Abstract Reaction of the Schiff‐base ligands 4‐(4‐NC~5~H~4~)C~6~H~4~C(H)=N(C~6~H~3~OH‐2‐__t__Bu‐5) (a) and (4‐NC~5~H~4~)C(H)=N(C~6~H~3~OH‐2‐__t__Bu‐5) (b) with palladium(II) acetate in toluene at 60 °C gave the tetranuclear orthometallated palladium complexes 1a and 1b, respectively, as air‐stab