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Synthesis and steric structure of 1,3(1,5)-dimethyl-2-phenyl-and -2,4-diphenyl-4-piperidols

โœ Scribed by T. D. Sokolova; I. P. Boiko; G. V. Cherkaev; A. S. Moskovkin; O. N. Khruleva


Publisher
Springer US
Year
1994
Tongue
English
Weight
379 KB
Volume
30
Category
Article
ISSN
0009-3122

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Synthesis of 3-Phenyl-, 3,4-Diphenyl-, a
โœ Dr. V. Bertini; Prof. Dr. P. Pino ๐Ÿ“‚ Article ๐Ÿ“… 1965 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 117 KB ๐Ÿ‘ 1 views

Acyl chlorides are split into acyl and chlorine radicals by light of wavelength 254 my. Since the dissociation energy of the chlorine-hydrogen bond is considerably larger than that of the acyl-hydrogen bond, substitution of the substrate by acyl radicals is observed on irradiation of acid chlorides.