Synthesis and stereochemistry of stereoisomeric 1,3-benzoxazino-1,3- and -3,1-benzoxazines
✍ Scribed by László Lázár; Ferenc Fülöp; Gábor Bernáth; Alajos Kálmán; Gyula Argay
- Book ID
- 112130080
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 1991
- Tongue
- English
- Weight
- 365 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0022-152X
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## Abstract The compound 3‐oxo‐1,3‐oxathiolane (6) and its **__cis__** ‐ and **__trans__** ‐ 2‐methyl (7,8), 4‐methyl (9,10), 5‐methyl (11,12) and 2‐__p__‐nitrophenyl (13,14) derivatives were prepared by oxidizing the corresponding 1,3‐oxathiolanes (1–5) with NaIO~4~ in water. The oxides were purif