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Synthesis and stereochemistry of 1-tert-butyl-2,5-dimethyl-3-piperidone

✍ Scribed by G. T. Katvalyan; é. A. Mistryukov

Book ID: 112445419
Publisher: Springer
Year: 1983
Tongue: English
Weight: 345 KB
Volume: 32
Category: Article
ISSN: 1573-9171
DOI: 10.1007/bf00954352

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In the title compound, C 26 H 36 N 2 O 3 S, the amide bearing the N-S bond has an s-cis conformation, whereas that bearing the N-tert-butyl group has an s-trans conformation, the N-N-C O torsion angles being À15.1 (2) and À174.3 (2) , respectively. The steric size of the N-tert-butyl group causes th