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Synthesis and stereochemical features of 2-oxo-3-cyano-1,2-thiaphosphorinanes

✍ Scribed by Irina L. Odinets; Natalya M. Vinogradova; Oleg I. Artyushin; Pavel V. Petrovskii; Konstantin A. Lyssenko; Michail Yu. Antipin; Tatyana A. Mastryukova

Book ID
111730212
Publisher
Royal Society of Chemistry
Year
1999
Tongue
English
Weight
177 KB
Volume
9
Category
Article
ISSN
0959-9436

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πŸ“œ SIMILAR VOLUMES

Intramolecular cyclization of Ο‰-haloalky
Intramolecular cyclization of Ο‰-haloalkylsubstituted thiophosphorylacetonitriles: Synthesis and stereochemistry of 3-cyano-2-oxo-1,2-thiaphosphacyclanes
✍ Irene L. Odinets; Natalya M. Vinogradova; Konstantin A. Lyssenko; Michail Yu. An πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 295 KB

## Abstract Intramolecular S‐alkylation in a series of ω‐haloalkyl‐substituted thiophosphorylacetonitriles **__5–7__** presents an effective synthetic route to the hitherto unknown 3‐cyano‐2‐oxo‐1,2‐thiaphospholanes **__14__** and thiaphosphinanes **__15__**. The compounds were obtained as a mixtur