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Synthesis and stereochemical confirmation of the HI/JK ring system of prymnesins, potent hemolytic and ichthyotoxic glycoside toxins isolated from the red tide alga

✍ Scribed by Makoto Sasaki; Takeshi Shida; Kazuo Tachibana

Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 152 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)01067-x

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✦ Synopsis

Stereocontrolled synthesis of the HI/JK ring model of the prymnesins, glyosidic toxins isolated from the red tide phytoflagellate Prymnesium parvum, is described. Comparison of its 1 H and 13 C NMR data with those of the natural toxins established the earlier stereochemical assignments.

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