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Synthesis and spectroscopic properties of the first phthalocyanine–nucleobase conjugates

✍ Scribed by Xi-you Li; Dennis K.P Ng

Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
143 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis

The adenine-containing zinc(II) phthalocyanines 3, 4a, and 4b have been prepared by standard O-alkylation of the tetrahydroxy analogue 1. These macrocycles exhibit rather strong intermolecular interactions resulting in a poor solubility in organic solvents and unusual spectral properties that are highly solvent-dependent. Self-assembly of the tetra-adenine phthalocyanine 3 and the thymine-containing 9,10-anthraquinone 6 through the Watson -Crick base-pairing interactions has also been demonstrated by fluorescence quenching experiments.

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ChemInform Abstract: Synthesis and Spect
ChemInform Abstract: Synthesis and Spectroscopic Properties of the First Phthalocyanine—Nucleobase Conjugates.
✍ Xi-you Li; Dennis K. P. Ng 📂 Article 📅 2001 🏛 John Wiley and Sons ⚖ 23 KB 👁 2 views

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