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Synthesis and spectroscopic properties of a new condensed phosphite oligomeric platinum(II) complex

โœ Scribed by Dickson, Mark K.; Fordyce, William A.; Appel, Donald M.; Alexander, Kenneth.; Stein, Paul.; Roundhill, D. Max.

Book ID
120834556
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
287 KB
Volume
21
Category
Article
ISSN
0020-1669

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The oxidative addition of XRCN to PtL4 yields cis-and/or trans-F'tX(RCN)L, (X = C1, Br; R = (CHS)~, n = 1, 2, 3; L = PPh,, PPh,CH,, AsPh,). L is readily displaced by more basic phosphines or by a diphosphine. In each case the trans complex is the thermodynamically more stable isomer and cis-lrulzs i