Synthesis and spectroscopic characterization of planar binuclear nickel(II) hexa(tert-butyl)phthalocyaninate
โ Scribed by Aleksandr Yu. Maksimov; Aleksei V. Ivanov; Yuliya N. Blikova; Larisa G. Tomilova; Nikolai S. Zefirov
- Book ID
- 119768056
- Publisher
- Royal Society of Chemistry
- Year
- 2003
- Tongue
- English
- Weight
- 112 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0959-9436
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The synthesis and characterization of the highly soluble tetra(tert-butyl)gallium(III) phthalocyanines (tBu) 4 PcGaCl ( 2) and (tBu) 4 PcGa(p-TMP) (3) is described. They were characterized by IR, UV/Vis, MS, and 1 H, 13 C, and 19 F NMR spectroscopy.
The hexa-tert-butyl substituted hexa-peri-hexabenzocoronene was synthesized in an overall yield of 83 % from 4-tert-butylphenylacetylene. The key step was the oxidative cyclodehydrogenation of hexa(4-tert-butylphenyl)benzene with anhydrous FeCl 3 in CH 2 Cl 2. The high solubility of hexa-tertbutyl-h