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Synthesis and spectroscopic characterization of cobalt(II) thiosemicarbazone complexes

โœ Scribed by El-Shazly, Rafat M.; Al-Hazmi, G. A. A.; Ghazy, S. E.; El-Shahawi, M. S.; El-Asmy, A. A.


Book ID
120655235
Publisher
Taylor and Francis Group
Year
2006
Tongue
English
Weight
266 KB
Volume
59
Category
Article
ISSN
0095-8972

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Phenyl pyruvate thiosemicarbazone (H2PPVATSC) coordinates in its binegative thiolate form to cobait(III) in the complex isolated from basic medium. An X-ray structure determination of the resulting meridional isomer was found to contain mutually eis sulphur, trans nitrogen, and trans oxygen donor at