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Synthesis and spectroscopic and x-ray structural studies of the mesitylphosphines Ph2Mes and PHMes2 (Mes = 2,4,6-Me3C6H2) and their lithium salts [Li(THF)3PHMes] and [{Li(OEt2)PMes2}2]

✍ Scribed by Bartlett, Ruth A.; Olmstead, Marilyn M.; Power, Philip P.; Sigel, Gary A.


Book ID
120281440
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
786 KB
Volume
26
Category
Article
ISSN
0020-1669

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2-(Me 2 NCH 2 )C 6 H 4 ]SnCl 3 (1) was prepared via (i) salt elimination reaction between RLi and SnCl 4 (1 : 1 molar ratio), in toluene solution, and (ii) redistribution reaction between [2-(Me 2 NCH 2 )C 6 H 4 ] 4 Sn and SnCl 4 (1 : 3 molar ratio), in the absence of a solvent. Recrystallization fr