Synthesis and spectral characteristics of a novel heterometallic binuclear complex on the basis of 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine
✍ Scribed by V. V. Pakal’nis; A. Yu. Sokolov; A. A. Slisenko; M. E. Borovitov; S. P. Tunik; O. V. Sizova
- Book ID
- 111460104
- Publisher
- Springer
- Year
- 2009
- Tongue
- English
- Weight
- 199 KB
- Volume
- 79
- Category
- Article
- ISSN
- 1070-3632
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📜 SIMILAR VOLUMES
The reaction of 3,6-diaryl-1,2,4,5-tetrazines and 2-aryl substituted acetonitriles, under basic conditions, leads unexpectedly to 3,5-diaryl-(NH)-1,2,4-triazoles in moderate yields. A mechanism is proposed.
a b s t r a c t Heating a neat 1:2 mixture of 2-picolylamine and 2-cyanopyridine followed by treatment of the resultant red gummy substance with aqueous KOH resulted in the isolation of 2,4,5-tris(2-pyridyl)imidazole (1a) as the major product and N-(3-(2-pyridyl)imidazo[1,5-a]pyridine)picolinamidine