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Synthesis and spectral characteristics of 4,4'-dimethoxythiobenzophenone

✍ Scribed by H.B. Williams; F.M. Hilburn; K. Yarbrough


Book ID
104102598
Publisher
Elsevier Science
Year
1964
Tongue
English
Weight
250 KB
Volume
31
Category
Article
ISSN
0003-2670

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Unusual formation of a thiacyclopent-2-e
✍ Kentaro Okuma; Yoshikazu Tsujimoto πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons 🌐 English βš– 84 KB

## Abstract The reaction of 4,4′‐dimethoxythiobenzophenone (**1a**) with tetracyanoethylene (TCNE) afforded an unusual type of 2:1 adduct with the structure of thiacyclopent‐2‐ene (**5a**). On the other hand, the reaction of thiobenzophenone (**1b**) with TCNE afforded the corresponding thiophene,