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Synthesis and spectral characterisation of new amido-ether Schiff bases

✍ Scribed by Oana Stamatoiu; Alexej Bubnov; Isabela Ţârcomnicu; Mircea Iovu

Book ID
103838145
Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
850 KB
Volume
886
Category
Article
ISSN
0022-2860

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The aldimines FcCH=NCH(Me)CH 2 OMe (1), FcCH=NCH 2 H 6 H 4 -2-OMe (2) and FcCH=N(CH 2 ) 3 NHMe (3) were obtained by reacting ferrocene aldehyde with the corresponding primary amines. Compounds 1±3 react with Me 2 Zn and Me 3 Al in a molar ratio 1 : 1 to the corresponding adducts 4±8. Reactions of 1