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Synthesis and Spectral and Structural Characterization of a New Series of Bis-Strapped Chiral Porphyrins Derived from L-Proline

✍ Scribed by Bernard Boitrel; Valérie Baveux-Chambenoît; Philippe Richard


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
461 KB
Volume
2001
Category
Article
ISSN
1434-193X

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✦ Synopsis


New chiral porphyrins were obtained in reasonable yields in three steps, starting from the αβαβ atropisomer of mesotetrakis(o-aminophenyl)porphyrin (TAPP). These potential catalysts for the enantioselective epoxidation of alkenes were obtained by the reaction of different linkers on the same L- prolinoyl-picket porphyrin. Their 1 H NMR spectral character- [a] L.


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