𝔖 Bobbio Scriptorium
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Synthesis and some properties of thiols, sulfides, and disulfides of the sulfolane series

✍ Scribed by T. É. Bezmenova; T. N. Varshavets; L. T. Matyash


Book ID
112326206
Publisher
Springer US
Year
1975
Tongue
English
Weight
331 KB
Volume
11
Category
Article
ISSN
0009-3122

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Rate constants for the reactions of tert-butoxy radicals (generated by the thermal decomposition of di-tert-butylperoxyoxalate) with several sulfur containing compounds have been measured a t 310 K in benzene. Hexanethiol ( k = 6.5 x lO'M-'s-') reacts considerably faster than alkyl sulfides and disu