Synthesis and solution thermodynamic study of rigidified and functionalised EGTA derivatives
✍ Scribed by Tei, Lorenzo; Baranyai, Zsolt; Botta, Mauro; Piscopo, Laura; Aime, Silvio; Giovenzana, Giovanni B.
- Book ID
- 118737236
- Publisher
- Royal Society of Chemistry
- Year
- 2008
- Tongue
- English
- Weight
- 192 KB
- Volume
- 6
- Category
- Article
- ISSN
- 1477-0520
- DOI
- 10.1039/B804195D
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The Gd(III) complexes of three new octadentate chelators, prepared by substitution of four, two, and one carboxylate groups of EGTA with phosphonate groups, have been investigated by 1 H and 17 O NMR relaxometric techniques in aqueous solutions. The analysis of the solvent proton relaxivity data as