## Abstract We report the synthesis of a novel pH‐responsive amphiphilic block copolymer poly(dimethylaminoethyl methacrylate)‐__block__‐poly(pentafluorostyrene) (PDMAEMA‐__b__‐PPFS) using RAFT‐mediated living radical polymerization. Copolymer micelle formation, in aqueous solution, was investigate
Synthesis and self-assembly of pH-responsive amphiphilic poly(ε-caprolactone)-block-poly(acrylic acid) copolymer
✍ Scribed by Cuizhen Li; Chunhua Gu; Yan Zhang; Meidong Lang
- Publisher
- Springer
- Year
- 2011
- Tongue
- English
- Weight
- 375 KB
- Volume
- 68
- Category
- Article
- ISSN
- 0170-0839
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Poly( 1-caprolactone) -poly(ethylene glycol) -poly( 1-caprolactone) triblock copolymers (PECL) covering a wide range of poly(ethylene glycol) (PEG) lengths were synthesized with alkali metal alkoxide derivatives of poly(ethylene glycol). The effects of various factors, such as amount of the initiato
## Abstract A poly(styrene‐__co__‐acrylic acid) copolymer was synthesized by surfactant‐free polymerization with the assistance of power ultrasound in water. Fourier transform infrared, NMR, and differential scanning calorimetry measurements revealed that the copolymer was random. Atomic force micr
## Abstract **Summary:** Novel, star‐shaped, amphiphilic block copolymers composed of fully degradable poly(caprolactone) were synthesized by sequential addition polymerization. In the first step, four‐arm macroinitiators were produced by ring‐opening polymerization of caprolactone by initiation wi