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Synthesis and Self-Assembly of Functionalized Donor−σ−Acceptor Molecules

✍ Scribed by Li, Hengfeng; Homan, Edwin A.; Lampkins, Andrew J.; Ghiviriga, Ion; Castellano, Ronald K.


Book ID
111954775
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
262 KB
Volume
7
Category
Article
ISSN
1523-7060

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Photoexcitation of a molecular assembly consisting of the donor and acceptor moieties dimethoxynaphthalene and dicyanoethylene rigidly separated by an approximately 15 A long, saturated hydrocarbon bridge results in a charge-separated state with a dipole moment of 77 D and a lifetime of 740 ns in be