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Synthesis and Self-Assembly of Amphiphilic Diblock Copolymers using a Fluorescently Labeled N-Alkoxyamine Initiator

✍ Scribed by Anna Tsimelzon; David Deamer; Rebecca Braslau

Book ID: 102490567
Publisher: John Wiley and Sons
Year: 2005
Tongue: English
Weight: 138 KB
Volume: 26
Category: Article
ISSN: 1022-1336
DOI: 10.1002/marc.200500608

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✦ Synopsis

Abstract

Summary: An initiator for nitroxide mediated ‘living’ free radical polymerization was prepared with a fluorescent tag attached to the initiating alkyl radical terminus. This was used to synthesize amphiphilic poly(acrylic acid)‐block‐polystyrene diblock copolymers, which self assembled in a tetrahydrofuran/buffer solution to form structures that are visible by fluorescence.
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