## Abstract Several rigid linear bisphenanthrolines with and without bulky groups at the bisimine sites were synthesized. For three representatives, the solid‐state structures were elucidated. Their potential for self‐assembled monolayers was explored by scanning tunneling microscopy (STM) at the s
Synthesis and Self-Assembly of a Rigid Exotopic Bisphenanthroline Macrocycle: Surface Patterning and a Supramolecular Nanobasket
✍ Scribed by Venkateshwarlu Kalsani; Horst Ammon; Frank Jäckel; Jürgen P. Rabe; Michael Schmittel
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 535 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0947-6539
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The design and synthesis of a novel bicyclic dilactam is described. It crystallizes from solution as a highly ordered self-assembly directed by intermolecular hydrogen bonding and hydrophobic interactions.
## Abstract A new macrocyclic compound has been synthesized by condensation of pyridine‐l‐oxide‐2, 6‐dialdehyde with diethylenetriamine. The self‐assembly behaviours were studied by X‐ray diffraction. The results show that the self‐assembly were controlled by intermolecular hydrogen bonds and π‐π s