Polymer-bound 2,2Π-bipyridine cobalt complexes PSBPY-Co, PSBPY-Cobipy, PSBPY-Co-oxine, and PSBPY-Co-phen (where PSBPY: polystyrene bound-2,2Πbipyridine; bipy: 2,2Π-bipyridine; phen: 1,10-phenanthroline) were synthesized and investigated by IR, X-ray photoelectric spectroscopy, thermogravimetry-diffe
Synthesis and selective catalytic oxidation properties of polymer-bound melamine copper(II) complex
β Scribed by Yun-Pu Wang; Yi Luo; Rong-Min Wang
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 359 KB
- Volume
- 33
- Category
- Article
- ISSN
- 1381-5148
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β¦ Synopsis
Polymer-bound melamine copper(I) complex was synthesized and characterized by IT-IR, ICP, XPS, UV and element analysis. 2-Phenyl-propene and p-methyl-1-phenylethanol were produced by selective oxidation of cumene, catalysed by the polymer-bound melamine Cu(1) complex under 1 atm of oxygen at 110Β°C.
π SIMILAR VOLUMES
Two percent divinylbenzene (DVB) -crosslinked polystyrene was prepared and functionalized to obtain its aldehyde analog. Amino porphyrins were anchored on this polymer support by Schiff base condensation. The anchoring positions were adjusted so as to obtain ortho-, meta-, and para-isomeric systems.