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Synthesis and resolution of a new P-chiral hydroxy phosphine

✍ Scribed by Joan Albert; J.Magali Cadena; Sergio Delgado; Jaume Granell

Book ID
108346642
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
92 KB
Volume
603
Category
Article
ISSN
0022-328X

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Synthesis, Resolution, and Reactivity of
Synthesis, Resolution, and Reactivity of Benzylmesitylphenylphosphine: A New P-Chiral Bulky Ligand
✍ Joan Albert; Ramon Bosque; J. Magali Cadena; Sergio Delgado; Jaume Granell; Guil πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 184 KB πŸ‘ 2 views

The synthesis of P,P'-dimesityl-P,P'-diphenyldiphosphine and benzylmesitylphenylphosphine is described as well as the resolution of the latter ligand by means of homochiral organometallic complexes. The absolute configuration of the phosphine is assigned by NMR spectra, using the homochiral palladac