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Synthesis and relaxivity of Gd(III), Fe(III) and Mn(II) complexes with dihydropyridine derivative of diethylenetriaminepentaacetic acid

โœ Scribed by Jianhua Chang; Shuzhan Zheng; Yajun Jian; Yinjuan Bai; Shiping Zhang


Publisher
SP Science China Press
Year
2005
Tongue
English
Weight
133 KB
Volume
48
Category
Article
ISSN
1674-7291

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Apoconalbumin binds \_Mn(II) at two sites with association constants of K1 = 7(%1) x lo4 and Kz = 0.4(?0.25) x lo4 M-l. The binding is tighter in the presence of excess bicarbonate resulting in K1 = l-8(\*0.2) X lo5 and K2 = 3(+2) X IO4 M-l. The electron paramagnetic resonance spectrum (at both 9 an