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Synthesis and redox properties of a diphosphene carrying a redox-active sterically protecting group

✍ Scribed by Kyoko Tsuji; Shigeru Sasaki; Masaaki Yoshifuji

Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 274 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(99)00466-9

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✦ Synopsis

The 2,6-dimesityl-4-[bis(4-methoxyphenyl)amino]phenyl group was developed as a sterically protecting group carrying a reversible redox site at the 4-position and was applied to the construction of a novel redox system composed of the diphosphene and triarylamine units.

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