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Synthesis and Reactivity of [(η6-Biphenylene)Mn(CO)3]+

✍ Scribed by Conor A. Dullaghan; Prof. Gene B. Carpenter; Prof. D. A. Sweigart

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
426 KB
Volume
3
Category
Article
ISSN
0947-6539

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## Abstract It has been shown that 2 equiv. of 2,3,5,6‐tetraphenylphosphinine (**2**) react with [Rh(COD)~2~][BF~4~] to yield the bis(η^1^‐phosphinine)Rh^I^ complex **6**, whose X‐ray crystal structure is presented. On the other hand, 2,6‐bis(trimethylsilyl)phosphinines **4** and **5** react with R