Synthesis and Reactivity of the First (Hydrosulfido)gold(III) Complex. Crystal Structure of the Derivatives NBu 4 [{Au(C 6 F 5 ) 3 } 2 SR] with the Isolobal Fragments R = H, AuPPh 3 , AgPPh 3 .

Syntheses and properties of the gold(I)

Syntheses and properties of the gold(I) complexes with bulky thiolates [Au(SR)]6and [Au(SR)(PPh3)] (R = C6H2Me3-2,4,6 or C6H2Prinf3supi-2,4,6), and the molecular structure of [Au(SC6H2Prinf3supi-2,4,6) (PPh3)]

✍ Yu Ying Tong; Armando J. L. Pombeiro; David L. Hughes; Raymond L. Richards 📂 Article 📅 1995 🏛 Springer 🌐 English ⚖ 424 KB

Reactions of [Au(acac)PPh3] with diphosp

Reactions of [Au(acac)PPh3] with diphosphine derivatives: different coordination modes of gold to the ligand systems. X-ray structure of [SPPh2C(AuPPh3)2PPh2CH(AuPPh3)COOMe]ClO4 and [Au5(C6F5){(SPPh2)2C}2(PPh3)]

✍ Gimeno, M. Concepcion; Laguna, Antonio; Laguna, Mariano; Sanmartin, Federico; Jo 📂 Article 📅 1993 🏛 American Chemical Society 🌐 English ⚖ 914 KB

Complexes with S-Donor Ligands. 5. † Syn

Complexes with S-Donor Ligands. 5. † Syntheses of the First (Hydrosulfido)- and Anionic Sulfidoorganogold(I) Complexes. Crystal and Molecular Structure of (Et 4 N) 2 [{Au(C 6 F 5 )} 3 (μ 3 -S)]·0.5MeC(O)Et

✍ Vicente, José; Chicote, María-Teresa; González-Herrero, Pablo; Grünwald, Claus; 📂 Article 📅 1997 🏛 American Chemical Society 🌐 English ⚖ 258 KB

Synthesis of intermediates in the C?H ac

Synthesis of intermediates in the C?H activation of acetone with 2-phenylazophenylgold(III) complexes and in the C?C coupling of aryl groups from diarylgold(III) complexes. Crystal and molecular structures of [Au{C6H3(N?NC6H4Me-4?)-2-Me-5}(acac-C)Cl](acac = acetylacetonate), cis-[Au(C6H4N?NPh-2)Cl2(PPh3)], and [Au(C6H4CH2NMe2-2)(C6F5)Cl]

✍ Vicente, Jos�; Berm�dez, Mar�a Dolores; Escribano, Jaime; Carrillo, Mar�a Pilar; 📂 Article 📅 1990 🏛 The Royal Society of Chemistry 🌐 English ⚖ 787 KB

Reactions of [Au(acac)PPh3] with diphosp

Reactions of [Au(acac)PPh3] with diphosphine derivatives: different coordination modes of gold to the ligand systems. X-ray structure of [SPPh2C(AuPPh3)2PPh2CH(AuPPh3)COOMe]ClO4 and [Au5(C6F5)((SPPh2)2C)2(PPh3)]. [Erratum to document cited in CA119(19):203522v]

✍ Gimeno, M. Concepcion; Laguna, Antonio; Laguna, Mariano; Sanmartin, Federico; Jo 📂 Article 📅 1994 🏛 American Chemical Society 🌐 English ⚖ 46 KB

The first example of a direct Cu+– bond.

The first example of a direct Cu+– bond. Synthesis and crystal structure of two closely related copper(I) hexafluorosilicate π-complexes with 1-allylbenzotriazole of [Cu2(C6H4N3(C3H5))2(H2O)2SiF6]·2H2O and [Cu2(C6H4N3(C3H5))2(CH3OH)2(H2O)2]SiF6 composition

✍ E.A. Goreshnik; Yu.I. Slyvka; M.G. Mys’kiv 📂 Article 📅 2011 🏛 Elsevier Science 🌐 English ⚖ 765 KB