✦ LIBER ✦

Synthesis and reactivity of ruthenium amide-phosphine complexes. Facile conversion of a ruthenium amide to a ruthenium amine via dihydrogen activation and orthometalation. X-ray structure of RuCl(C6H4PPh2)[NH(SiMe2CH2PPh2)2]

✍ Scribed by Fryzuk, Michael D.; Montgomery, Craig D.; Rettig, Steven J.

Book ID: 126329518
Publisher: American Chemical Society
Year: 1991
Tongue: English
Weight: 943 KB
Volume: 10
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om00048a025

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Synthesis of a New Multidentate Phosphan

Synthesis of a New Multidentate Phosphane Ligand C6H2(CH2PPh2)4-1,2,4,5 − X-ray Structure of a Dinuclear Ruthenium(II)-Bridged Complex: [{RuCl2(PPh3)}2{C6H2(CH2PPh2)4-1,2,4,5-P,P′,P′′,P′′′}]

✍ Pablo Steenwinkel; Sebastiaan Kolmschot; Robert A. Gossage; Paulo Dani; Nora Vel 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 581 KB

The tetrakis(phosphane oxide) C 6 H 2 {CH 2 P(O)Ph 2 } 4 -1,2,4,5 (5), has been prepared in high yield from the Arbuzov reaction of C 6 H 2 (CH 2 Br) 4 -1,2,4,5 (4), with excess (7 equiv.) of Ph 2 POEt. Subsequent reduction of 5 with HSiCl 3 (12 equiv.) in C 6 H 4 Cl 2 -1,2 afforded the new tetrapho

ChemInform Abstract: Synthesis of a New

ChemInform Abstract: Synthesis of a New Multidentate Phosphane Ligand C6H2 (CH2PPh2)4-1,2,4,5 — X-Ray Structure of a Dinuclear Ruthenium(II)-Bridged Complex: [{RuCl2(PPh3)}2{C6H2 (CH2PPh2)4-1,2,4,5-P,P′,P′′,P′′′}].

✍ P. STEENWINKEL; S. KOLMSCHOT; R. A. GOSSAGE; P. DANI; N. VELDMAN; A. L. SPEK; G. 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 37 KB 👁 1 views

Synthesis, Chemistry, and Catalytic Acti

Synthesis, Chemistry, and Catalytic Activity of Ruthenium Diaminodiphosphane Complexes − Crystal Structures of trans-[RuCl2{κ3-Ph2PC6H4CH=NC6H10N(H)CH2C6H4PPh2}(PPh3)] and cis-[RuCl2{κ4-Ph2PC6H4CH=NC6H10N(H)CH2C6H4PPh2}]

✍ Wai-Kwok Wong; Xiao-Ping Chen; Wei-Xiong Pan; Jian-Ping Guo; Wai-Yeung Wong 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 362 KB 👁 2 views

Ruthenium Cyclopentadienyl Aryldiazenido

Ruthenium Cyclopentadienyl Aryldiazenido Complexes. Synthesis of [Cp‘Ru(PR 3 ) 2 (N 2 C 6 H 4 OMe)][BF 4 ] 2 and [Cp‘RuCl(PPh 3 )(N 2 C 6 H 4 OMe)][BF 4 ] (Cp‘ = Cp, Cp*) and X-ray Crystal Structure of [CpRu(PPh 3 ) 2 (N 2 C 6 H 4 OMe)][BF 4 ] 2 , an Aryldiazenido Complex with a Large N−N−C(aryl) Angle and Near-Linear Ru−N−N−C(aryl) Skeleton

✍ Fan, Li; Einstein, Frederick W. B.; Sutton, Derek 📂 Article 📅 2000 🏛 American Chemical Society 🌐 English ⚖ 244 KB

Sequential C−H and C−Ru Bond Formation a

Sequential C−H and C−Ru Bond Formation and Cleavage during the Thermally Induced Rearrangement of Aryl Ruthenium(II) Complexes with [C 6 H 3 (CH 2 NMe 2 ) 2 -2,6] - as a Bidentate η 2 - C,N Coordinated Ligand. The Crystal Structures of the Isomeric Pairs [RuCl{η 6 -C 10 H 14 }{η 2 - C,N -C 6 H 3 (CH 2 NMe 2 ) 2 -2, n }] ( n = 4 or 6) and [Ru(η 5 -C 5 H 5 ){η 2 - C,N -C 6 H 3 (CH 2 NMe 2 ) 2 -2, n }(PPh 3 )] ( n = 4 or 6)

✍ Steenwinkel, Pablo; James, Stuart L.; Gossage, Robert A.; Grove, David M.; Kooij 📂 Article 📅 1998 🏛 American Chemical Society 🌐 English ⚖ 283 KB