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Synthesis and Reactivity of Ortho-Palladated Arylureas. Synthesis and Catalytic Activity of a C,N,C Pincer Complex. Stoichiometric Syntheses of Some N-Heterocycles

✍ Scribed by Vicente, José; Abad, José-Antonio; López-Serrano, Joaquín; Jones, Peter G.; Nájera, Carmen; Botella-Segura, Luis


Book ID
120275824
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
278 KB
Volume
24
Category
Article
ISSN
0276-7333

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✍ Claudio Bianchini; Géraldine Lenoble; Werner Oberhauser; Sébastien Parisel; Fabr 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 160 KB

## Abstract The __ortho__‐palladation of the iminophosphane ligand 6‐phenyl‐2‐[(2,6‐diisopropylphenyl)imino]pyridine (HL) with Pd(OAc)~2~ and PdCl~2~(PhCN)~2~ in benzene yields the neutral Pd–C,N,N pincer complexes Pd(OAc)(κ^3^‐C,N,N‐L) (1) and PdCl(κ^3^‐C,N,N‐L) (2), respectively. In the presence