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Synthesis and Reactivity of N -Heterocycle-B(C 6 F 5 ) 3 Complexes. 4. Competition between Pyridine- and Pyrrole-Type Substrates toward B(C 6 F 5 ) 3 : Structure and Dynamics of 7-B(C 6 F 5 ) 3 -7-azaindole and [7-Azaindolium] + [HOB(C 6 F 5 ) 3 ] -

✍ Scribed by Focante, Francesca; Camurati, Isabella; Resconi, Luigi; Guidotti, Simona; Beringhelli, Tiziana; D'Alfonso, Giuseppe; Donghi, Daniela; Maggioni, Daniela; Mercandelli, Pierluigi; Sironi, Angelo


Book ID
124079185
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
244 KB
Volume
45
Category
Article
ISSN
0020-1669

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Synthesis and Reactivity of (C6F5)3BN-he
✍ Alessandra Bonazza; Isabella Camurati; Simona Guidotti; Nicoletta Mascellari; Lu πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 242 KB

## Abstract Summary: The reaction of pyrroles and indoles with perfluoroarylboranes produces 1:1 B‐N complexes that contain highly acidic sp^3^ methylenes. These complexes are stable and can be used as a proton source for the generation of methylmetallocene cations. Indole is preferred over pyrrole