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Synthesis and reactivity of mixed pentafluorophenylpalladium(I)-platinum(I) derivatives molecular structure of ClPt(μ-dppm)2 Pd(C6F5)

✍ Scribed by Juan Fornies; Francisco Martinez; Rafael Navarro; Adelaida Redondo; Milagros Tomas; Alan J. Welch


Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
991 KB
Volume
316
Category
Article
ISSN
0022-328X

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Treating [Cp\*V(l-Cl) 2 ] 3 (Cp\* = C 5 Me 5 ) and [(2,6-i-Pr 2 C 6 H 3 N) 2 MoMe 2 ], respectively, with Me 3 SnF afforded the title compounds [Cp\*V(l-F) 2 ] 4 (1) and [(2,6-i-Pr 2 C 6 H 3 N) 2 MoF 2 ] ´THF ( 2). 1 has a tetrameric structure, in which four V atoms can be regarded as being arranged