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Synthesis and Reactivity of [Ir(C 2 H 4 ) 2 Tpm Me2 ]PF 6 (Tpm Me2 = Tris(3,5-dimethylpyrazolyl)methane): Comparison with the Analogous Tp Me2 Derivatives (Tp Me2 = Hydrotris(3,5-dimethylpyrazolyl)borate)

✍ Scribed by Padilla-Martínez, Itzia I.; Poveda, Manuel L.; Carmona, Ernesto; Monge, M. Angeles; Ruiz-Valero, Caridad


Book ID
120227463
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
174 KB
Volume
21
Category
Article
ISSN
0276-7333

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✍ Chen-Long Lee; Pang-Yen Yang; Chang-Wei Su; Jhy-Der Chen; Lin-Shu Liou; Ju-Chun 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 151 KB

From a solution prepared by a reaction of Mo 2 (O 2 CCH 3 ) 4 with KTp\* (Tp\*= hydridotris(3,5-dimethylpyrazolyl)borate, HB(Me 2 Pz) 3 ), in diglyme at room temperature followed by addition of excess (CH 3 ) 3 SiBr to the red solution in refluxing THF, the complexes [HB(Me 2 Pz) 3 )BH][Br 3 Mo(m-Br