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Synthesis and reactivity of hydrotris(pyrazolyl)borate σ-hydrocarbyl uranium(IV) complexes

✍ Scribed by Manuela Silva; Noémia Marques; A. Pires de Matos


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
384 KB
Volume
493
Category
Article
ISSN
0022-328X

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## Abstract The syntheses of two tetravalent uranium alkoxide‐carbene complexes are reported, [UIL~3~], and [UL~4~] where L=OCMe~2~CH~2~[1‐C(NCHCHN__i__Pr)]. The latter shows dynamic behaviour of the alkoxycarbene ligands in solution at room temperature, and the crystal structure of [UL~4~] shows t