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Synthesis and Reactivity of an α-Stannyl β-Silyl Enamide

✍ Scribed by Laurianne Timbart; Jean-Christophe Cintrat


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
96 KB
Volume
8
Category
Article
ISSN
0947-6539

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ChemInform Abstract: A Highly Diastereos
✍ M. YAMAMOTO; K. ITOH; K. KISHIKAWA; S. KOHMOTO 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 35 KB

A Highly Diastereoselective Synthesis of α-Substituted-β-hydroxy Compounds from Corresponding β-Stannyl Compounds. -Anti compounds, e.g. (II), are completely converted to their syn analogues (IV) using Lewis acids such as SnCl 4 or TiCl 4 . AlCl 3 , ZrCl 4 , or ZnCl 2 are not suitable for this reac