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Synthesis and Reactivity of a Polycyclic, Oxa-Bridged Phosphaalkene

✍ Scribed by Sven G. Ruf; Uwe Bergsträßer; Manfred Regitz

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
370 KB
Volume
2000
Category
Article
ISSN
1434-193X

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## Abstract Cyclopropanecarboxaldehyde (1 a), cyclopropyl methyl ketone (1 b), and cyclopropyl phenyl ketone (1 c) were reacted with [Ni(cod)~2~] (cod=1,5‐cyclooctadiene) and PBu~3~ at 100 °C to give η^2^‐enonenickel complexes (2 a–c). In the presence of PCy~3~ (Cy=cyclohexyl), 1 a and 1 b reacted