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Synthesis and reactivity of 22,23-methylene-2,3,17,18-tetramethyl-23-hydro-1, 19-[21H,24H]-bilindion-10-enium trifluoroacetate

✍ Scribed by J. A. de Groot; R. van der Steen; J. Lugtenburg

Publisher: Elsevier Science
Year: 2010
Tongue: English
Weight: 443 KB
Volume: 101
Category: Article
ISSN: 0165-0513
DOI: 10.1002/recl.19821010706

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✦ Synopsis

Abstract

The biliverdinium salt 1 has been prepared in high yield and its behaviour towards nucleophiles studied. The reactions have been found to occur selectively on the central carbon atom 10 and to lead to bilirubin systems. In addition, the photoisomerisation of the bilirubin model compound 5, prepared from 1, has been investigated.

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