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Synthesis and reactivities of novel η2-(C,O) alkylphenylketene complexes of nickel. Coordination-mode switching reaction of the ketene ligand

✍ Scribed by Akira Miyashita; Ryu-ji Sugai; Jun-ichi Yamamoto


Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
592 KB
Volume
428
Category
Article
ISSN
0022-328X

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The reactions of the bis(trimethylsilyl)acetylene permethylmetallocene complexes Cp 2 M(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (1), M = Zr (2)) with H 2 O and CO 2 were studied and compared to those of the corresponding metallocene complexes Cp 2 M(L)(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (3), L = ± ; M = Zr,