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Synthesis and reactions of perfluoro-α-oxides derived from trimers of hexafluoropropene

✍ Scribed by A.Ya. Zapevalov; T.I. Filyakova; N.V. Peschansky; M.I. Kodess; I.P. Kolenl

Book ID
104150149
Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
41 KB
Volume
29
Category
Article
ISSN
0022-1139

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## Abstract Hexafluoropropene reacts with aromatic azine __N__‐oxides under mild conditions to produce fluorides of 2‐heteroarylperfluoropropionic acids. The reaction proceeds as 1,3‐dipolar cycloaddition followed by spontaneous scission of the NO bond in the isoxazolidine ring and elimination of