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Synthesis and reactions of di, tri- and tetra-nuclear cationic complexes derived from bis(μ-methylenepentamethylcyclopentadienyl)dirhodium: the crystal structure of tetranuclear [{(C5Me5Rh-μ-CH2)2}2(μ-CN)2](PF6)2

✍ Scribed by Jesus Martinez; Harry Adams; Neil A. Bailey; Peter M. Maitlis


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
545 KB
Volume
405
Category
Article
ISSN
0022-328X

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✍ Antonio Antiñolo; Iván Dorado; Mariano Fajardo; Andrés Garcés; Isabel López-Sol 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 254 KB 👁 1 views

## Abstract The preparation of a family of dinuclear monocyclopentadienyl imidoniobium and ‐tantalum complexes was achieved by two different synthetic routes. The diimido complexes [{M(Cp′)Cl~2~}~2~(μ‐1,__i__‐NC~6~H~4~N)] [Cp′ = η^5^‐C~5~H~4~SiMe~3~, M = Nb, __i__ = 4 (1); Cp′ = η^5^‐C~5~H~4~SiMe~3