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Synthesis and reactions of conformational isomers of a stable selenenic acid bearing a bridged calix[6]arene framework

✍ Scribed by Kei Goto; Toshiyuki Saiki; Shigehisa Akine; Takayuki Kawashima; Renji Okazaki

Publisher: John Wiley and Sons
Year: 2001
Tongue: English
Weight: 78 KB
Volume: 12
Category: Article
ISSN: 1042-7163
DOI: 10.1002/hc.1031

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✦ Synopsis

Abstract

A stable selenenic acid bearing a bridged calix[6]arene framework fixed in the 1,2,3‐alternate conformation was synthesized. Its properties were compared with those of its conformational isomer fixed in the cone conformation, indicating that the reactivity of the endohedral SeOH group can be regulated by the conformation of the calix[6]arene framework. © 2001 John Wiley & Sons, Inc. Heteroatom Chem 12:195–197, 2001

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