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Synthesis and reactions of a chelated carbene-olefin complex of cyclopentadienyliron

✍ Scribed by Daniel L. Reger; Stephen A. Klaeren

Book ID
103223896
Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
753 KB
Volume
342
Category
Article
ISSN
0022-328X

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E, they are also not hydrolyzed by conc. hydrochloric acid. 3a-c can be deprotonated with sodium hydroxide and acylated at the nitrogen. Although in the 1,2,4-diazaphospholes a 1,3-diamino-2phosphaallyl system is still formally present, the ring closure is associated with an essential change: the c