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Synthesis and reactions of 3-alkoxy-2H-azirines

โœ Scribed by L. Ghosez; F. Sainte; M. Rivera; C. Bernard-Henriet; V. Gouverneur

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
477 KB
Volume
105
Category
Article
ISSN
0165-0513

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In the presence of molybdenum hexacaroonyl, 3-phenyl-2H-azirines and aceLylene carooxylic acid esters react via the unusual splitting of the C,N-double bond to give 2H-pyrroles or pyrroles. 2H-Azirines have been shown to undergo C-C bond cleavage photolytically, whilst in ground-state reactions all