Synthesis and rapid expansion in supercritical carbon dioxide through porous sintered metal plate of poly(1,1,2,2-tetrahydroperfluorodecyl acrylate)

Synthesis of Polyurethane/Poly(1,1,2,2-t

Synthesis of Polyurethane/Poly(1,1,2,2-tetrahydroperfluorodecyl acrylate) Particles in Supercritical Carbon Dioxide

✍ Benjamin Renault; Eric Cloutet; Patrick Lacroix-Desmazes; Henri Cramail 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 320 KB

## Abstract A new range of end‐functionalized poly(1,1,2,2‐tetrahydroperfluorodecyl acrylate)s was synthesized by ATRP. Such macromonomers were used as reactive and steric stabilizers for the preparation of original core‐shell polyurethane particles in supercritical carbon dioxide. The nature of th