Synthesis and radical polymerization of multi-functional acrylic ester bearing a 2,2-bis(alkoxycarbonyl)ethyl group as 2-substituent

Preparation and polymerization behavior

Preparation and polymerization behavior of 2-[2,2,2-tris-(alkoxycarbonyl)ethyl]acrylic ester as a sterically congested monomer

✍ Bunichiro Yamada; Seiya Kobatake; Osamu Konosu 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 482 KB

Methyl 2-[2,2,2-tris(methoxycarbonyl)ethyl]acrylate and methyl 2-[2,2,2-tris(ethoxycar-bony1)ethyllacrylate [M(TE)EA] were synthesized for the first time by the reaction of methyl 2-(bromomethyl)acrylate with the corresponding tris(alkoxycarbony1)methane in the presence of triethylamine at room temp